Publication list VESPA 1

Bischofer, B., Hagemann, S., Altmaier, M., Banik, N., Bosbach, D., Bracke, G., Brendler, V., Curtius, H., Finck, N., Franzen, C., Gaona, X., Geckeis, H., Heberling, F., Herm, M., Kindlein, J., Marsac, R., Metz, V.,  Muñoz, A., Rozov, K., Schäfer, T., Scharge, T., Totskiy, Y., Wiedemann, M., Yalcintas, E., (2016): VESPA - Behaviour of Long-Lived Fission and Activation Products in the Nearfield of a Nuclear Waste Repository and the Possibilities of their Retention, GRS Project Report 274, ISBN 978-3-944161-55-6, 744 p.

Curtius, H., Kaiser, G., Rozov, K., Neumann, A., Dardenne, K., Bosbach, D. (2013): Preparation and characterization of Fe-, Co-, and Ni-containing Mg-Al-Layered Double Hydroxides. Clays and Clay Minerals 61, 424–439.
DOI 10.1346/CCMN.2013.0610503

Finck, N., Dardenne, K., Bosbach, D., Geckeis, H. (2012): Selenide Retention by Mackinawite. Environmental Science & Technology 46: 10004-10011.

Heberling, F., Eng, P., Denecke, M.A., Lutzenkirchen, J., Geckeis, H., (2014): Electrolyte layering at the calcite(104)-water interface indicated by Rb+- and Se(VI) K-edge resonant interface diffraction. Physical Chemistry Chemical Physics 16: 12782-12792.

Heberling, F., Vinograd, V.L., Polly, R., Gale, J.D., Heck, S., Rothe, J., Bosbach, D., Geckeis, H., Winkler, B. (2014): A thermodynamic adsorption/entrapment model for selenium(IV) coprecipitation with calcite. Geochimica et Cosmochimica Acta 134: 16-38.

Huber, F. M., Totskiy, Y., Marsac, R., Schild, D., Pidchenko, I., Vitova, T., Kalmykov, S., Geckeis, H., Schäfer, T. (2017): Tc interaction with crystalline rock from Äspö (Sweden): Effect of in-situ rock redox capacity. Applied Geochemistry, 80, 90-101.

Jordan, N.; Franzen, C., Lützenkirchen, J.; Foerstendorf, H., Hering, D., Weiß, S., Heim, K., Brendler, V. (2018): Adsorption of selenium(VI) onto nano transition alumina. Environmental Science, Nano 5, 1661-1669.

Jordan, N.; Müller, K.; Franzen, C.; Brendler, V. (2013): Temperature impact on the sorption of selenium(VI) onto anatase. Journal of Colloid and Interface Science 390, 170-175.

Jordan, N.; Ritter, A.; Foerstendorf, H.; Scheinost, A. C.; Weiß, S.; Heim, K.; Grenzer, J.; Mücklich, A.; Reuther, H. (2013): Adsorption mechanism of selenium(VI) onto maghemite. Geochimica et Cosmochimica Acta 103, 63-75.

Jordan, N.; Ritter, A.; Scheinost, A. C.; Weiß, S.; Schild, D.; Hübner, R. (2014): Selenium(IV) Uptake by Maghemite (γ-Fe₂O₃). Environmental Science & Technology 483, 1665-1674.

Kobayashi, T., Scheinost, A.C., Fellhauer, D., Gaona, X., Altmaier, M. (2013): Redox behavior of Tc(VII)/Tc(IV) under various reducing conditions in 0.1 M NaCl solutions. Radiochimica Acta 101: 323-332.

Kretzschmar, J.; Jordan, N.; Brendler, E.; Tsushima, S.; Franzen, C.; Foerstendorf, H.; Stockmann, M.; Heim, K.; Brendler, V. (2015): Spectroscopic evidence for selenium(IV) dimerization in aqueous solution. Dalton Transactions 44, 10508-10515.

Mayordomo, N.; Foerstendorf, H.; Lützenkirchen, J.; Heim, K.; Weiss, S.; Alonso, U.; Missana, T.; Schmeide, K.; Jordan, N. (2018): Selenium(IV) sorption onto γ-Al2O3: a consistent description of the surface speciation by spectroscopy and thermodynamic modeling. Environmental Science & Technology 52, 581-588.

Nie, Z.; Finck, N.; Heberling, F.; Pruessmann, T.; Liu, C.; Lützenkirchen, J., (2017): Adsorption of Selenium and Strontium on Goethite: EXAFS Study and Surface Complexation Modeling of the Ternary Systems. Environmental Science & Technology 2017, 51, (7), 3751-3758.

Polly, R.; Heberling, F.; Schimmelpfennig, B.; Geckeis, H. (2017): Quantum Chemical Investigation of the Selenite Incorporation into the Calcite (10-14) Surface. The Journal of Physical Chemistry C 2017, 121, 20217-20228.

Rozov, K., Curtius, H., Neumann, A., Bosbach, D. (2013): Synthesis, characterization and stability properties of Cl-bearing hydrotalcite-pyroaurite solids. Radiochimica Acta 101, 101-109.
DOI 10.1524/ract.2013.2007

Rozov, K., Curtius, H., Bosbach, D. (2015): Preparation and estimation of thermodynamic properties of Fe(II)­, Co(II)-, Ni(II)- and Zr(IV)- containing Layered Double Hydroxides. Key Topics in Deep Geological Disposal: Conference Report, Köln 2014. Deutsche Arbeitsgemeinschaft für Endlagerforschung (DAEF), KIT Scientific Reports 7696.

Totskiy, Y., PhD (2015):Tc-migration in advection/diffusion controlled natural systems: Influence of ferrous iron pool. KIT, Karlsruhe, Germany.

Totskiy, Y., Geckeis, H., Schäfer, T. (2012): Sorption of Tc(VII) on Äspö diorite (ÄD). 1st Workshop Proceedings of the Collaborative Project “Crystalline Rock Retention Processes” (7th EC FP CP CROCK), KIT Scientific Reports, pp. 97-106.

Totskiy, Y., Schäfer, T., Huber, F., Schild, D., Geckeis, H. Kalmykov, S., (2013): Tc(VII) sorption on natural granitic rocks and synthetic magnetite. Final Workshop Proceedings, 7th EC FP CP-CROCK, KIT Scientific Reports., pp 197-210.

Yalcintas, PhD (2015): Redox, solubility and sorption chemistry of technetium in dilute to concentrated saline systems. KIT, Karlsruhe, Germany, KIT Scientific Reports 7703.

Yalcintas, E., Gaona, X., Altmaier, M. (2016): Release on thermodynamic Pitzer Tc(IV) hydrolysis model to THEREDA.

Yalcintas, E., Gaona, X., Altmaier, M., Dardenne, K., Polly, R. and Geckeis, H. (2016): Thermodynamic description of Tc(IV) solubility and hydrolysis in dilute to concentrated NaCl, MgCl2 and CaCl2 solutions. Dalton Transactions 2016, 45, 8916-8936.

Yalcintas E., Gaona, X., Scheinost, A., Kobayashi, T., Altmaier, M. and Geckeis, H. (2014): Redox chemistry of Tc(VII)/Tc(IV) in dilute to concentrated NaCl and MgCl2 solutions. Radiochim Acta 2015, 103, 57-72.

Yalcintas E., Scheinost, A., Gaona, X. and Altmaier, M. (2016): Systematic XAS study on the reduction and uptake of Tc by magnetite and mackinawite. Dalton Transactions 2016, DOI: 10.1039/C6DT02872A.

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